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| Keira Knightley | Georgiana Spencer, Duchess of Devonshire |
| Ralph Fiennes | The Duke of Devonshire |
| Charlotte Rampling | Lady Spencer |
| Dominic Cooper | Charles Grey |
| Hayley Atwell | Bess |
| Simon McBurney | Charles Fox |
| Aidan McArdle | Richard Sheridan |
| John Shrapnel | Gen. Grey |
| Alistair Petrie | Heaton |
Though adored by the people, the Duchess of Devonshire is not content to sit as a pretty figurehead. Determined to be a major player in affairs of state, she rises to the forefront of the Whig Party and helps usher in reform in late-1700s England. The one thing it seems she cannot do is win the heart of her husband .
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