| William Bell | Himself |
| Jerry Butler | |
| The Chi-Lites | Themselves |
| Isaac Hayes | Himself |
| Sam Moore | Himself |
| Ann Peebles | Herself |
| Wilson Pickett | Himself |
| Sir Mack Rice | Himself |
| Carla Thomas | Herself |
| Rufus Thomas | Himself |
| Mary Wilson | Herself |
Filmmakers Chris Hegedus and D.A. Pennebaker showcase performers of R & B and soul from the 1950s to the 1970s.
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