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| Ray Milland | Prof. Vernon K. Simpson/King Kelly |
| Jean Peters | Deborah Greenleaf |
| Paul Douglas | Monk Lanigan |
| Ed Begley | Edgar Stone |
| Ted de Corsia | Manager Jimmy Dolan |
| Ray Collins | Prof. Alfred Greenleaf |
| Jessie Royce Landis | Mrs. Greenleaf |
| Alan Hale Jr. | Schmidt |
| Bill Murphy | Tommy Isbell |
| William E. Green | Prof. Joe Fosythe (uncredited) |
| Edward Keane | Jack Bell (uncredited) |
| Gene Evans | Batter Mueller (uncredited) |
| Al Eben | Parker (uncredited) |
| Ruth Lee | Miss Collins (uncredited) |
| John Butler | Fan Visiting with Debbie (uncredited) |
| Ray Teal | Mac |
| Debra Paget | Alice (uncredited) |
| Mae Marsh | Greenleaf's Maid (uncredited) |
A college chemistry professor, Vernon Simpson, invents a substance that keeps insects away from wood. But after a baseball crashes through the window and gets coated in the fluid, Simpson discovers that the ball repels wood. To further his experiment, Simpson tries out as a pitcher with the St. Louis Cardinals and becomes a master of the screwball, propelling him into the spotlight as a star player, much to the confusion of his fiancée, Deborah .
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