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| Steve Martin | Himself (Host) (segment "Pines of Rome") |
| Itzhak Perlman | Himself (Violinist/Host) (segment "Pines of Rome") |
| Quincy Jones | Himself (Host) (segment "Rhapsody in Blue") |
| Bette Midler | Hostess |
| James Earl Jones | Himself (Host) (segment "Carnival of the Animals") |
| Penn Jillette | Host (segment "The Sorcerer's Apprentice") |
| Teller | Host (segment "The Sorcerer's Apprentice") |
| James Levine | Himself (conductor) |
| Angela Lansbury | Hostess |
| Wayne Allwine | Mickey Mouse (segment "Pomp and Circumstance") |
| Tony Anselmo | Donald Duck (segment "Pomp and Circumstance") |
| Kathleen Battle | Feature Soprano (segment "Pomp and Circumstance") |
| Walt Disney | Mickey Mouse (segment "The Sorcerer's Apprentice") |
| Ralph Grierson | Himself (Pianist) (segment "Rhapsody in Blue") |
| Leopold Stokowski | Himself (Conductor) (segment "The Sorcerer's Apprentice") (archive footage) |
The works of Beethoven, Stravinsky, Saint-Saens and others come to life in a blend of music and animation.
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